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Borji, Mehdi. (1404). Numerical investigation of the effect of the electrochemical oxidation of carbon monoxide on the performance of a planar solid oxide fuel cell fuelled by synthesis gas. فناوری آموزش, 15(1), 129-148. doi: 10.22061/jcarme.2026.11493.2523
Mehdi Borji. "Numerical investigation of the effect of the electrochemical oxidation of carbon monoxide on the performance of a planar solid oxide fuel cell fuelled by synthesis gas". فناوری آموزش, 15, 1, 1404, 129-148. doi: 10.22061/jcarme.2026.11493.2523
Borji, Mehdi. (1404). 'Numerical investigation of the effect of the electrochemical oxidation of carbon monoxide on the performance of a planar solid oxide fuel cell fuelled by synthesis gas', فناوری آموزش, 15(1), pp. 129-148. doi: 10.22061/jcarme.2026.11493.2523
Borji, Mehdi. Numerical investigation of the effect of the electrochemical oxidation of carbon monoxide on the performance of a planar solid oxide fuel cell fuelled by synthesis gas. فناوری آموزش, 1404; 15(1): 129-148. doi: 10.22061/jcarme.2026.11493.2523

Numerical investigation of the effect of the electrochemical oxidation of carbon monoxide on the performance of a planar solid oxide fuel cell fuelled by synthesis gas

Journal of Computational & Applied Research in Mechanical Engineering (JCARME)
مقاله 10، دوره 15، شماره 1 - شماره پیاپی 29، مهر 2025، صفحه 129-148    اصل مقاله (772.89 K)
نوع مقاله: Research Paper
شناسه دیجیتال (DOI): 10.22061/jcarme.2026.11493.2523
نویسنده
Mehdi Borji*
Department of Mechanical Engineering, La.C., Islamic Azad University, Lahijan, Iran.
تاریخ دریافت: 06 آذر 1403،  تاریخ بازنگری: 30 دی 1404،  تاریخ پذیرش: 05 بهمن 1404 
چکیده
A comprehensive investigation has been conducted into the direct internal reforming planar type solid oxide fuel cell (DIR-PSOFC) through numerical analysis. The mathematical modeling of DIR-PSOFC is achieved through the implementation of conservation equations and a comprehensive electrochemical model. The synthesis gas fuel is introduced into the fuel channel, where both carbon monoxide (CO) and hydrogen (H2) undergo electrochemical oxidation. Gas flows are treated as plug flows with a co-flow configuration. Results of the simulation are then compared with and without the inclusion of carbon monoxide electrochemical oxidation. This comparison encompasses temperature fluctuations along the cell's longitudinal axis and the mole fraction variations of all gaseous species along the cel length, in addition to the electrical performance of the SOFC. It has been demonstrated that CO accounts for only 20% of the total current density. The contribution of CO to the generation of electric current at the inlet is 15%. At the point of maximum current density, the value is 16.17%. The cell operating voltage, power density, and fuel efficiency have been demonstrated to exhibit an enhancement, with an augmentation observed from 0.68 to 0.75 V, 3411.396 to 3739.130 W/m2, and 45.83% to 50.23%, respectively, when CO is used as a reactant in the anode side TPB. It has been determined that the electrochemical reaction of CO results in elevated heat generation within the cell, which in turn enhances the operating temperature. Consequently, the activation and ohmic losses are diminished, thereby improving the local current density and cell operating voltage.
کلیدواژه‌ها
SOFC؛ Synthesis gas fuelled؛ Direct internal reforming؛ Co electrochemical reaction؛ Comprehensive numerical investigation
مراجع
[1]  S. C. Singhal, “High Temperature SolidOxide Fuel Cells: Fundamentals, Design and Applications.” Oxford, UK: Elsevier Ltd, (2003).

[2]   J. Larminie, A. Dicks, and M.S. McDonald, “Fuel cell systems explained”. Vol. 2, J. Wiley Chichester, UK, (2003).

[3]  H. Khoshkam, K. Atashkari, and M. Borji, “Unsteady state numerical study of carbon deposition on the performance of solid oxide fuel cell and variation of porosity”. J.  Compu. & Appl. Res. in Mech. Eng. (JCARME), Vol. 12, No. 2, pp. 247-261, (2023).

[4]   C. O. Colpan, I. Dincer, and F. Hamdullahpur, “Thermodynamic modeling of direct internal reforming solid oxide fuel cells operating with syngas”, Int. J. Hydrogen Energy, Vol. 32, No. 7, pp. 787-795, (2007).

[5]  M. Andersson, J. Yuan, and B. Sundén, “SOFC modeling considering hydrogen and carbon monoxide as electrochemical reactants”, J. Power Sources, Vol. 232: pp. 42-54, (2013).

[6]   S. A. Hajimolana, M. A. Hussain, W. M. Ashri Wan Daud, M. Soroush and A. Shamiri, “Mathematical modeling of solid oxide fuel cells: A review”, Renew. Sustain. Energy Rev., Vol. 15, No. 4, pp. 1893-1917, (2015).

[7]  N. Panwar, R. Kothari, and V. Tyagi, “Thermo chemical conversion of biomass–Eco friendly energy routes”, Renew. Sustain. Energy Rev., Vol. 16, No. 4, pp. 1801-1816, (2012).

[8]  R. Toonssen, S. Sollai, P. V. Arvind, N. Woudstra, and A. H. M. Verkooijen, “Alternative system designs of biomass gasification SOFC/GT hybrid systems”,  Int. J. Hydrogen Energy, Vol. 36, No. 16, pp. 10414-10425, (2011).

[9]    C. Bang-Møller and M. Rokni, “Thermodynamic performance study of biomass gasification, solid oxide fuel cell and micro gas turbine hybrid systems”, J. Energy Convers. Manag., Vol. 51, No. 11, pp. 2330-2339, (2010).

[10]  S. Bedogni, S. Campanari, P. Iora, L. “Experimental analysis and modeling for a circular-planar type IT-SOFC”, J. Power Sources, Vol.171, No. 2, pp. 617-625, (2007).

[11]  K. Chen, Z. Lu, N. Ai, X. Chen, X. Huang and W. Su, “Experimental study on effect of compaction pressure on performance of SOFC anodes”, J. Power Sources, Vol. 180, No. 1, pp. 301-308, (2008).

[12]  S. Seidler, M. Henke, J. Kallo, W. G. Bessler, U. Maier and K. A. Friedrich, “Pressurized solid oxide fuel cells: Experimental studies and modeling”, J. Power Sources, Vol. 196, No. 17, pp. 7195-7202, (2011).

[13]  S. Kakac, A. Pramuanjaroenkij, and X.Y. Zhou, “A review of numerical modeling of solid oxide fuel cells”,  Int. J. Hydrogen Energy, Vol. 32, No. 7, pp. 761-786, (2007).

[14]  H. Hesami, M. Borji, and J. Rezapour, “Three-dimensional numerical investigation on the effect of interconnect design on the performance of internal reforming planar solid oxide fuel cell”, Korean J. Chem. Eng., Vol. 38, No. 12, pp. 2423-2435, (2021).

[15]  H. Hesami, M. Borji, and J. Rezapour, “A comprehensive three-dimensional modeling of an internal reforming planar solid oxide fuel cell with different interconnect designs”, J. Solid State Electrochem., Vol. 25, No. 10, pp. 2639-2664, (2021).

[16] A. Ashar, Y. Gu, G. Jackson, R. Braun, “Achieving high power density in SOFCs for transportation applications: A model-based assessment of YSZ- and GDC-based electrolyte architectures”. J. Energy Convers. Manag., Vol. 348, Part B, pp. 120661, (2026).

[17] F. Peng, H. Li, W. Liu, Q. Zhu, “Multiphysics modeling and deep learning-driven multi-objective optimization of the oxygen electrode microstructure in solid oxide electrolysis cell considering oxygen distribution uniformity and residual stress-induced failure”. J. Energy Convers. Manag., Vol. 348, Part A, pp. 120648, (2026).

[18] M. L. Ferrari, “Solid oxide fuel cell hybrid system: control strategy for stand-alone configurations”. J. Power Sources, Vol. 195, No.3, pp. 685-7, (2010).

[19] F. Zabihian, and A.S. Fung, “Performance analysis of hybrid solid oxide fuel cell and gas turbine cycle (part I): Effects of fuel composition on output power”, J. Energy Inst., Vol. 87, No. 1, pp. 18-27, (2014).

[20] H. Ozcan, and I. Dincer, “Performance evaluation of an SOFC based trigeneration system using various gaseous fuels from biomass gasification”,  Int. J. Hydrogen Energy, Vol. 40, No. 24, pp. 7798-7807, (2015).

[21] M. Hatef, E. Golamian, S.M. Seyed Mahmoudi, Ali Saber Mehr, “Enhancing efficiency and reduced CO2 emision in hybrid biomass gasification with integrated SOFC-MCFC system based on CO2 recycle”. J. Energy Convers. Manag., Vol. 313, pp. 118611, (2024).

[22] X. Zhou, W. Chen, B. Zhang, “Proposed hybrid system with integrated SOFC, gas turbine, and compressor-assisted absorption refrigerator using [mmim]DMP/CH3OH as working fluid”. J. Energy, Vol. 261, Part B, pp. 125301, (2022).

[23] Z. Wang, X. Yang, J. Xu, X. Wang, F. Deng, Z. Huang, “Scheduling of integrated energy system considering the combined operation of SOFC and dynamic hydrogen-blended gas turbine. ”,  Int. J. Hydrogen Energy, Vol. 190,  pp. 152221, (2025).

[24] P. Aguiar, D. Chadwick, and L. Kershenbaum, “Modelling of an indirect internal reforming solid oxide fuel cell”, Chem. Eng. Sci., Vol. 57, No. 10, pp. 1665-1677, (2002).

[25] P. Aguiar, C.S. Adjiman, and N.P. Brandon, “Anode-supported intermediate temperature direct internal reforming solid oxide fuel cell. I: model-based steady-state performance”, J. Power Sources, Vol. 138, No. 1-2, pp. 120-136, (2004).

[26] O. Corigliano, G. Florio, and P. Fragiacomo, “A numerical simulation model of high temperature fuel cells fed by biogas”, Energy Sources, Part A, Vol. 34, No. 2, pp. 101-110, (2011).

[27] M. A. Abdelkareem, W. H. Tanveer, E. T. Sayed, M. E. H. Asad, A. Allagui and S. W. Cha, “On the technical challenges affecting the performance of direct internal reforming biogas solid oxide fuel cells” Renew. Sustain. Energy Rev., Vol. 101, pp. 361-375, (2019).

[28] E. Achenbach, “Three-dimensional and time-dependent simulation of a planar solid oxide fuel cell stack”, J. Power Sources, Vol. 49, No. (1-3), pp. 333-348, (1994).

[29] H. Iwai, H., Y. Yamamoto, M. Saito and H. Yoshida, “Numerical simulation of intermediate-temperature direct-internal-reforming planar solid oxide fuel cell”, J. Energy, Vol. 36, No. 4, pp. 2225-2234, (2011).

[30] J. J. Ramírez-Minguela, V. H. Rangel-Hernandez, J. A. Alfaro-Ayala, A. R. Uribe-Ramirez, J. M. Mendoza-Miranda, J. M. Belman-Flores and B. Ruiz-Camacho, “Energy and entropy study of a SOFC using biogas from different sources considering internal reforming of methane”, Int. J. Heat Mass Trans., Vol. 120, pp. 1044-1054, (2018).

[31] A. Burt, I. B. Celik, R. S. Gemmen and A. V. Smirnov, “A numerical study of cell-to-cell variations in a SOFC stack”, J. Power Sources, Vol. 126, No. 1-2, pp. 76-87, (2004).

[32] M. Iwata, T. Hikosaka, M. Morita, T. Iwanari, K. Ito, K. Ondo, Y. Esaki, Y. Sakaki and S. Nagata, “Performance analysis of planar-type unit SOFC considering current and temperature distributions”, Solid State Ion., Vol. 132, No. 3-4, pp. 297-308, (2000).

[33] S. Nagata, A. Momma, T. Kato and Y. Kasuga, “Numerical analysis of output characteristics of tubular SOFC with internal reformer”, J. Power Sources, Vol. 101, No. 1, pp. 60-71, (2001).

[34] P. Aguiar, C. Adjiman, and N. Brandon, “Anode-supported intermediate-temperature direct internal reforming solid oxide fuel cell: II. Model-based dynamic performance and control”, J. Power Sources, Vol. 147, No. 1-2, pp. 136-147, (2005).

[35] H. Yakabe, T. Ogiwara, M. Hishinuma and I. Yasuda, “3-D model calculation for planar SOFC”, J. Power Sources, Vol. 102, No. 1-2, pp. 144-154, (2001).

[36] D. Bhattacharyya, R. Rengaswamy, and C. Finnerty, “Isothermal models for anode-supported tubular solid oxide fuel cells”, Chem. Eng. Sci., Vol. 62, No. 16, pp. 4250-4267, (2007).

[37] M. Borji, K. Atashkari, N. Nzadeh and M. Masoumpour, “Modeling, parametric analysis and optimization of an anode-supported planar solid oxide fuel cell”, Proc. Inst. Mech. Eng. C. J. Mech. Eng. Sci., Vol. 229, No. 17, pp. 3125-3140, (2015).

[38] R. Suwanwarangkul, E. Croiset, E. Entchev, S. Charojrochkul, M. D. Pritzker, M. W. Fower, P. L. Douglas, S. Chewathanakup and H. Mahaudom, “Experimental and modeling study of solid oxide fuel cell operating with syngas fuel”, J. Power Sources, Vol. 161, No. 1, pp. 308-322, (2006).

[39] C. Stiller, “Design, operation and control modelling of SOFC/GT hybrid systems”, Norwegian University of Science and Technology (NTNU), Norway, (2006).

[40] S. Chan, S., K. Khor, and Z. Xia, “A complete polarization model of a solid oxide fuel cell and its sensitivity to the change of cell component thickness”, J. Power Sources, Vol. 93, No. 1-2, pp. 130-140, (2001).

[41] B. E. Poling, J.M. Prausnitz, and J.P. O'connell, “The properties of gases and liquids”, 5th ed., Mcgraw-hill New York, (2001).

 

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